Development of reversible photoinduced electron transfer
Redox Photochemistry
Abstract
Photoinduced electron transfer and charge separation is one of the most important phenomena in Universe. It plays an important role in processes essential for life, such as photosynthesis, respiration, protein folding and biocatalysis. It is also highly relevant for solar cells, batteries, molecular electronics and smart materials.
The thesis will focus on development of systems for reversible charge transfer between two redox-active centres. The transfer of charge will be in both directions controlled by photoinduced electron transfer and both states will be stabilized by follow-up chemical reaction (intramolecular cyclization, protonation and others).
Reversible photoinduced electron transfer will be used for dipole reorientation, control of charges and counterions and regulation of electrostatic interactions. These unique properties will be further used in design of novel materials and devices in molecular electronics.
The candidate will perform synthesis and characterization of organic redox-active molecules and will study their properties.
Highly motivated and skilful candidate will have the opportunity to extend his/her graduate training in physical and organic chemistry by learning electrochemical, photochemical and advanced spectroscopic methods.
Field of study: Organic chemistry
Universities
PhD students must be enrolled in a partner university and will be employed by the IOCB Prague at the same time (part-time or full time), which results in a competitive salary (a scholarship from the university + a salary from the IOCB). Each university has its own process, terms, and deadlines for PhD applications, which is separate from the IOCB recruitment process. You may discuss the details with the respective PI.
How to apply
Please return to the PhD projects at IOCB Prague – Call for Applications 2025 page and follow the instructions.