Study of photochemistry of non-classical electrophiles and Lewis acids
Redox Photochemistry
Abstract
Electrophiles and Lewis acids are among the most common intermediates utilized for catalytic reactions. Many attempts have been made to characterize and classify the strength and reactivity of these electron deficient species. However, the classical concept of electrophilicity and Lewis acidity starts to fall apart when open-shell (radicals, radical ions) and excited states are considered.
The thesis will focus on development of electrophilic systems with open-shell and electronically excited electronic structure capable of various non-classical interactions with nucleophilic and radical partners. This unique behaviour will not only be applied in novel catalytic reactions but if will be used in re-formulation of rules for chemical bonding between open-shell and electronically excited species.
The candidate will perform synthesis and characterization of organic non-classical electrophiles and Lewis acids and will study their catalytic properties and non-covalent interactions.
Highly motivated and skilful candidate will have the opportunity to extend his/her graduate training in organic chemistry by learning electrochemical, photochemical and physicochemical methods.
Field of study: Organic chemistry
Universities
PhD students must be enrolled in a partner university and will be employed by the IOCB Prague at the same time (part-time or full time), which results in a competitive salary (a scholarship from the university + a salary from the IOCB). Each university has its own process, terms, and deadlines for PhD applications, which is separate from the IOCB recruitment process. You may discuss the details with the respective PI.
How to apply
Please return to the PhD projects at IOCB Prague – Call for Applications 2025 page and follow the instructions.